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The Defect Chemistry of Metal Oxides »

Book cover image of The Defect Chemistry of Metal Oxides by Donald Morgan Smyth

Authors: Donald Morgan Smyth, D. M. Smyth
ISBN-13: 9780195110142, ISBN-10: 0195110145
Format: Hardcover
Publisher: Oxford University Press, USA
Date Published: June 2000
Edition: (Non-applicable)

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Author Biography: Donald Morgan Smyth

Lehigh University

Book Synopsis

The Defect Chemistry of Metal Oxides is a unique introduction to the equilibrium chemistry of solid inorganic compounds with a focus on metal oxides. Accessible to students with little or no background in defect chemistry, it explains how to apply basic principles and interpret the related behavior of materials. Topics discussed include lattice and electronic defects, doping effects, nonstoichiometry, and mass and charge transport. The text distinctly emphasizes the correlation between the general chemical properties of the constituent elements and the defect chemistry and transport properties of their compounds. It covers the types of defects formed, the effects of dopants, the amount and direction of nonstoichiometry, the depths of acceptor and donor levels, and more. Concluding chapters present up-to-date and detailed analyses of three systems: titanium dioxide, cobalt oxide and nickel oxide, and barium titanate. The Defect Chemistry of Metal Oxides is the only book of its kind that incorporates sample problems for students to solve. Suitable for a variety of courses in materials science and engineering, chemistry, and geochemistry, it also serves as a valuable reference for researchers and instructors.

Table of Contents

Preface
1Introduction1
2A Few Useful Crystal Structures4
3Lattice Defects and the Law of Mass Action21
4Intrinsic Ionic Disorder34
5Extrinsic Ionic Disorder57
6Defect Complexes and Associates75
7Ionic Transport91
8Intrinsic Electronic Disorder118
9Extrinsic Electronic Disorder138
10Intrinsic Nonstoichiometry162
11Extrinsic Nonstoichiometry197
12Titanium Dioxide217
13Cobalt Oxide and Nickel Oxide239
14Barium Titanate253
15Order versus Disorder283
Index291

Subjects