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The Chemical Bond in Inorganic Chemistry: The Bond Valence Model »

Book cover image of The Chemical Bond in Inorganic Chemistry: The Bond Valence Model by I. David Brown

Authors: I. David Brown
ISBN-13: 9780199298815, ISBN-10: 0199298815
Format: Paperback
Publisher: Oxford University Press, USA
Date Published: June 2006
Edition: (Non-applicable)

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Author Biography: I. David Brown

McMaster University (Emeritus)

Book Synopsis

This book describes the bond valence model, a description of acid-base bonding which is becoming increasingly popular particularly in fields such as materials science and mineralogy where solid state inorganic chemistry is important. Recent improvements in crystal structure determination have allowed the model to become more quantitative. Unlike other models of inorganic chemical bonding, the bond valence model is simple, intuitive, and predictive, and can be used for analysing crystal structures and the conceptual modelling of local as well as extended structures. This is the first book to explore the theoretical basis of the model and to show how it can be applied to synthetic and solution chemistry. It emphasizes the separate roles of the constraints of chemistry and of three-dimensional space by analysing the chemistry of solids. Many applications of the model in physics, materials science, chemistry, mineralogy, soil science, surface science, and molecular biology are reviewed. The final chapter describes how the bond valence model relates to and represents a simplification of other models of inorganic chemical bonding.

Booknews

The valence bond model is a description of acid-base bonding useful in fields such as materials science and mineralogy. This book outlines the theoretical basis of the model and shows how it can be applied to synthetic and solution chemistry. It emphasizes the separate roles of the constraints of chemistry and of three-dimensional space by analyzing the chemistry of solids. Many applications of the model in physics, materials science, chemistry, mineralogy, soil science, surface science, and molecular biology are reviewed. A final chapter explains how the bond valence model relates to and represents a simplification of other models of inorganic chemical bonding. Brown is professor emeritus at the Department of Physics and Astronomy, McMaster University, Canada. Annotation c. Book News, Inc., Portland, OR (booknews.com)

Table of Contents

Prologue1
1Historical introduction3
ITheory11
2The ionic bond13
3The bond valence model26
IIChemistry41
4Anion and cation bonding strengths43
5Liquids53
6Cation coordination number64
7Hydrogen bonds75
8Electronically distorted structures90
9Physical properties of bonds105
IIISolids119
10Space and space groups121
11Modelling inorganic structures134
12Lattice-induced strain164
IVApplications and implications179
13Applications181
14Chemical implications of the bond valence model207
Appendices223
App. 1Bond valence parameters224
App. 2Space group spectra233
App. 3Solution of the network equations240
App. 4Cation and anion bonding strengths244
App. 5References to the ICSD and the CSD247
References253
List of symbols271
Index273

Subjects