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Structured Catalysts and Reactors » (REV)

Book cover image of Structured Catalysts and Reactors by Andrzej Cybulski

Authors: Andrzej Cybulski (Editor), Jacob A. Moulijn
ISBN-13: 9780824723439, ISBN-10: 0824723430
Format: Hardcover
Publisher: Taylor & Francis, Inc.
Date Published: November 2005
Edition: REV

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Author Biography: Andrzej Cybulski

Book Synopsis

Interest in structured catalysts is steadily increasing due to the already proven, as well as potential, advantages of these catalysts. Updating the comprehensive coverage of the first edition published in 1998 with the latest science and applications, Structured Catalysts and Reactors, Second Edition gives detailed information on all aspects of structured catalysts and reactors, including: materials, mass transfer, selectivity, activity, and stability; catalyst preparation, design, and characterization; process development; modeling and optimization; reactor design; and operation costs and considerations.

The book first examines how monolithic catalysts are used to clean exhaust gas from gasoline engines, treat industrial off-gases, burn fuels in commercial settings, and synthesize chemicals in two- and three-phase processes. It discusses configurations, microstructure, physical properties, and manufacture of ceramic and metallic monoliths before directing its focus to arranged catalysts and structured packings in terms of mass transfer. The book then explores catalytically active membranes and filters, featuring metallic membranes, permeation mechanisms, preparation and modeling, commercial membranes, and the latest applications, such as zeolitic membranes. Finally, several chapters present techniques for incorporating catalytic species into the structured catalyst support and controlling catalyst nanoporosity.

This book conveys the scientific as well as economic advantages of using these unconventional catalytic techniques. With over 1500 references, tables, drawings, and photographs, as well as in-depth discussions and a new approach to catalytic processes, Structured Catalysts and Reactors, Second Edition is an essential reference for anyone working with or studying catalysis.

Booknews

Examines a type of catalyst that shows promise of eliminating the chemical and thermal distortions often encountered when using fixed- bed reactors in the chemical industry. After an overview, 22 independent treatments cover reactors using monolithic or honeycomb catalysts in which there is no convective mass transfer over a cross- section of the reactor; those in which there is such transfer; monolithic reactors with permeable walls, called membrane reactors; and preparing and characterizing catalysts. The specific topics include the computer-aided characterization and design of a catalyst pore structure, ceramic catalyst supports and filters for diesel exhaust aftertreatment, parallel-passage and lateral-flow reactors, modeling monolith reactors in three-phase processes, the unconventional utilization of monolithic catalysts for gas-phase reactions, and metal and coated-metal catalysts. Annotation c. by Book News, Inc., Portland, Or.

Table of Contents

Ch. 1The present and the future of structured catalysts : an overview1
Pt. IReactors with structured catalysts where no convective mass transfer over a cross section of the reactor occurs (monolithic catalysts = honeycomb catalysts)19
Ch. 2Ceramic catalyst supports for gasoline fuel21
Ch. 3Metal and coated metal catalysts71
Ch. 4Autocatalysts : past, present, and future109
Ch. 5Treatment of volatile organic carbon (VOC) emissions from stationary sources : catalytic oxidation of the gaseous phase147
Ch. 6Monolithic catalysts for NO[subscript x] removal from stationary sources171
Ch. 7Catalytic fuel combustion in honeycomb monolith reactors215
Ch. 8Monolithic catalysts for gas-phase syntheses of chemicals243
Ch. 9Modeling of automotive exhaust gas converters311
Ch. 10Monolithic catalysts for three-phase processes355
Ch. 11Two-phase segmented flow in capillaries and monolith reactors393
Ch. 12Modeling and design of monolith reactors for three-phase processes435
Ch. 13Film flow monolith reactors479
Pt. IIReactors with structured catalysts where convective mass transfer over the cross section of the reactor occurs507
Ch. 14Parallel-passage and lateral-flow reactors509
Ch. 15Structured packings for reactive distillation539
Pt. IIIMonolithic reactors with permeable walls (membrane reactors)551
Ch. 16Catalytic filters for flue gas cleaning553
Ch. 17Reactors with metal and metal-containing membranes579
Ch. 18Inorganic membrane reactors615
Ch. 19Ceramic catalysts, supports, and filters for diesel exhaust after-treatment663
Ch. 20Zeolite membranes : modeling and application701
Pt. IVCatalyst preparation and characterization749
Ch. 21Transformation of a structured carrier into a structured catalyst751
Ch. 22Structuring catalyst nanoporosity779

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