Category Books

Photoinitiated Polymerization »

Authors: Kevin D. Belfield (Editor), James V. Crivello
ISBN-13: 9780841238138, ISBN-10: 0841238138
Format: Hardcover
Publisher: An American Chemical Society Publication
Date Published: March 2003
Edition: (Non-applicable)

Author Biography: Kevin D. Belfield

University of Central Florida

Rensselaer Polytechnic Institute

Book Synopsis

Known as UV-curing, the technology of photoininitiated polymerizations is a hot field for research and applications in coatings, adhesives, and printing inks as well as microelectronic encapsulation, photo- and stereolithography and holographic data storage. Advances in the field are good news for the environment, because the use of the technology can reduce or eliminate the use of solvents. Selected expanded papers from a RadTech symposium held in Chicago (August 2001) report on recent research in free radical and cationic photopolymerizations, novel photopolymerization chemistry, and new and emerging applications. Editors Belfield and Crivello are affiliated, respectively, with the University of Central Florida and Rensselaer Polytechnic Institute. The book is distributed by Oxford University Press. Annotation ©2003 Book News, Inc., Portland, OR

	Preface
1	N-Vinylamides and Reduction of Oxygen Inhibition in Photopolymerization of Simple Acrylate Formulations	2
2	Spectroscopic Investigation of Three-Component Initiator Systems	15
3	A Mechanistic Description of the Sensitized N-Substituted Maleimide Initiated Photopolymerization of an Acrylate Monomer	27
4	Photoinitiation of Acrylates via Sensitized Phthalimide Derivatives	41
5	Photoinitiated Polymerization of Selected Thiol-ene Systems	52
6	Allyl Ethers in the Thiol-ene Reaction	65
7	Mechanistic Aspects of Maleimide-Donor Photocopolymerizations	76
8	Photoiniated Cross-Linking Polymerization of Monomer Blends	92
9	Synthesis and Photochemistry of Monodisperse Oligometric-Polymeric Photoinitiators	105
10	Kinetics of Photopolymerization of Acrylate Coatings	113
11	Effect of Preorganization Due to Hydrogen Bonding on the Rate of Photoinitiated Acrylate Polymerization	127
12	Photoinitiator Triplet States and Photoinitiating Radical-Monomer Interaction: Investigation through Time-Resolved Photothermal Techniques	140
13	Oxygen Inhibition Effect on Surface Properties of UV-Curable Acrylate Coatings	152
14	Oxygen and Radical Photopolymerization in Films	165
15	Synergistic Free Radical Effects in Photoinitiated Cationic Polymerization	178
16	Initiation of Cationic Polymerization by Addition-Fragmentation Reactions: Bifunctional Addition-Fragmentation Agents as Photoinitiators for Cationic Polymerization	187
17	Diazonium Salts as Cationic Photoinitiators: Radical and Cationic Aspects	202
18	2,3-Dihydrofuran: A Special Vinyl Ether for Cationic Photopolymerization	213
19	Photosensitization of Onium Salt Initiated Cationic Photopolymerizations by Carbazole Monomers, Polymers, and Oligomers	219
20	Phenothiazine Photosensitizers for Onium Salt Photoinitiated Cationic Polymerization	231
21	Visible and Long-Wavelength Cationic Photopolymerization	242
22	Synthesis and Photoinitiated Cationic Polymerization of Organic-Inorganic Hybrid Resins	253
23	The Photoinitiated Cationic Polymerization of 3,4-Epoxy-1-butene	266
24	Synthesis and Photoinitiated Cationic Polymerization of Fluoroalkyl Propenyl Ethers	277
25	Cationic Photopolymerization of 2-Phenyloxetanes	285
26	Photocurable Pressure-Sensitive Adhesives Using Alkyl Oxetane	296
27	Photocationic Curable Silsesquioxanes Having Oxetanyl Group	306
28	Thermomechanical Studies of Photoinitiated Cationic Polymerization of a Cycloaliphatic Epoxy Resin	317
29	Harvesting the Fields of Inorganic and Organometallic Photochemistry for New Photoinitiators	332
30	Quaternary Ammonium N,N-Dimethyldithiocarbamates as Photobase Generators	351
31	Synthesis and Photochemical Reaction of High-Performance UV-Curing Oligomers	363
32	Photopolymerization Kinetics of Nanostructured Polymers Templated by Lyotropic Liquid Crystals	378
33	Photopolymerization of Silica-Filled Composites: Encapsulants for Microelectronic Devices	389
34	Photocurable, Hydrophobic Oligomers Based on Liquid Polybutadienes	400
35	UV-Curable Acrylated Oligomers: Effect of Structural Variation on Liquid and Cured Film Properties	412
36	Real-Time Fluorescence for Determining the Relative Sensitivities of Reactive and Non-Reactive Fluorescent Probes	426
37	Continuous Photopolymerization in a Novel Thin Film Spinning Disc Reactor	437
38	Pulsed Laser Polymerization of Methyl Methacrylate Using Wilkinson's Catalyst as a Photoinitiator	451
39	Two-Photon Photoinitiated Polymerization	464
40	Fluorinated Distyrylbenzene Containing Copolymers for Photoinduced Formation of Anisotropic Materials as Photoalignment Layers for Liquid Crystals	482
41	UV-Curing of Fluorinated Systems: Synthesis and Properties	499
42	Autohesion of Polyethylene Plates by the Photoinduced Grafting of Methacrylamide	511
	Author Index	525
	Subject Index	527